Fig. 4: Verification of the suitability of the strategy for different structures.

a Mechanism of stepwise confinement in a polymeric compound. b Vertical excitation energy of the optimized and simplified model B3. c Phosphorescence decay behavior under 254 nm at ambient conditions in different systems. d, e Phosphorescence spectra (d) and lifetime (e) excited by 300 nm (enlargement unit is μs). f CIE coordinates of each example after crosslinking. Fluo. fluorescence, Phos. phosphorescence, Exc. excitation, ISC intersystem crossing, Non-rad. nonradiative decay.