Fig. 7: Mechanistic manifold for Mb-catalyzed olefin cyclopropanation with benzyl diazoketone.
From: Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone
Global mechanistic picture describing productive and competing pathways in Mb-catalyzed styrene cyclopropanation with BDK as derived from the described mechanistic, spectroscopic, computational, and structural data. TOF turnover frequency.
