Fig. 4: Operando pulse experiments and reaction mechanism of MSR.
From: Designing Cu0−Cu+ dual sites for improved C−H bond fracture towards methanol steam reforming
MS signals for the pulse experiments of a methanol and b methanol-water (1:2) over 4.25Cu/Cu(Al)Ox at 240 °C, respectively. c Relative intensity of the reaction intermediates normalized by CO2 signal based on the results of (a) and (b). d MS signals for the pulse experiments of methyl formate and methyl formate-water (1:2) over 4.25Cu/Cu(Al)Ox from 150 to 240 °C, respectively. e Schematic illustration for MSR reaction mechanism (HCOOCH3* route).
