Fig. 3: Scope of linear allylic alkylation.
From: Catalytic stereodivergent allylic alkylation of 2-acylimidazoles for natural product synthesis
Unless otherwise specified, all the reactions were carried out by using 1 (0.1 mmol), 2 (0.15 mmol), Ni(OAc)2 (10 mol%), (S,S)−5c (10 mol%), and Cs2CO3 (0.2 mmol) in dichloromethane (DCM) (2.0 mL) at 10 °C for 1-4 days. aWith Cs2CO3 (0.1 mmol) at 0 °C. bWith 2 (0.3 mmol).
