Fig. 3: Scope of the cine-cyanation, cine-amination and cine-amidation of alkenes by thianthrenation.

The reaction was carried out using 1 (0.15 mmol), 2 (0.10 mmol), KF (3.0 equiv) in CH₃CN (0.1 M) at room temperature for 10 h unless otherwise stated. Isolated yield is shown. ^aThe reaction was conducted at 50 ^oC. ^bThe reaction was conducted at 50 ^oC for 24 h. ^cThe reaction was conducted using K₂CO₃ (1.0 equiv). rr = ratio of regioisomers. ^dThe reaction was conducted on 5.0 mmol scale using K₂CO₃ (1.0 equiv). ^eThe reaction was conducted using Cs₂CO₃ (1.0 equiv).