Fig. 5: Mechanistic study.
From: Efficient palladium-catalyzed electrocarboxylation enables late-stage carbon isotope labelling
a DFT study of the carboxylation of V and VI with the BINAP ligand. b Cyclic voltammetry of oxidative addition complex 32 in argon and CO2 atmosphere. c Consumed charge during the reaction. d Control reactions. e Effect of adding ethanol in the cyclic voltammetry in DMF and acetonitrile (ACN). f Scope of the carboxylation reaction with amide-free solvent.
