Fig. 3: Difluorocarbene-induced allylic and benzyl Stevens rearrangement of tertiary amines.
From: Difluorocarbene-induced [1,2]- and [2,3]-Stevens rearrangement of tertiary amines
Reaction condition: a4/5 (1 equiv., 0.2 mmol), 2d (1.5 equiv., 0.3 mmol), H2O (15 equiv.), Rb2CO3 (3 equiv.), CH3CN (2 mL) at 90 °C for 12 h under argon.
