Fig. 5: Scope of substrates derived from complex molecules.
From: Difluorocarbene-induced [1,2]- and [2,3]-Stevens rearrangement of tertiary amines
Reaction condition: a10 (1 equiv., 0.2 mmol), 2d (1.5 equiv., 0.3 mmol), H2O (5 equiv.), K3PO4 (3 equiv.), CH3CN (2 mL) at 90 °C for 12 h under argon.
