Fig. 1: Synthesis and characterizations of [Os] complexes. | Nature Communications

Fig. 1: Synthesis and characterizations of [Os] complexes.

From: Silicon photocathode functionalized with osmium complex catalyst for selective catalytic conversion of CO2 to methane

Fig. 1: Synthesis and characterizations of [Os] complexes.

a Synthesis of przpOs and trzpOs. b Single-crystal X-ray structure of przpOs from the side and top views (thermal ellipsoids: 30%). c UV-visible (UV-vis) absorption and photoluminescence (PL) spectra of 10-5 M przpOs and trzpOs in dichloromethane. d PL lifetimes of 10-5 M przpOs and trzpOs in N2 and CO2 atmosphere.

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