Fig. 5: Direct carbonylation of natural gas alkanes without using transition metals and syngas. | Nature Communications

Fig. 5: Direct carbonylation of natural gas alkanes without using transition metals and syngas.

From: Main-group compounds selectively activate natural gas alkanes under room temperature and atmospheric pressure

Fig. 5: Direct carbonylation of natural gas alkanes without using transition metals and syngas.The alternative text for this image may have been generated using AI.

a Transformation from n-butane to 2-methylbutyraldehyde. b Transformation from propane to isobutyraldehyde. c Transformation from ethane to propionic aldehyde. d Reaction mechanism of transformation from DAC1-propane to isobutyraldehyde. Yields were determined by 1H-NMR spectra using 1, 3, 5-trimethoxybenzene as internal standard. ORF = OC(CF3)3.

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