Table 1 Summarized key parameters and design principles for EOOR systems
Substances | Products | Oxidation Potential | Relative Change of θOH* a | Reaction Complexity | Altered ΔGEq.2 | M3+δ−OH* Requirement |
|---|---|---|---|---|---|---|
Aldehyde | Carboxylic acid | Low | 25–55% | Simple | −5 to 5 meV | Relatively low level of θOH* |
Alcohol | Aldehyde | Highest b | 13–20% | Simple | 0–12 meV b | Relatively low level of θOH* |
Carboxylic acid | Moderate | 25–35% | Moderate | 5–10 meV | Balanced θOH*/θsub* | |
Amine | Nitrile | High | 20–32% | Complex | 20–35 meV | High level of θOH* |
