Fig. 4: Synthetic applications and Mechanistic studies.
From: Copper-catalyzed photoinduced carbonylation of C1-C3 gaseous alkanes
a 1 mmol scale-up reaction. b Cu-catalyzed carbonylation of ethane with DEAD. c Synthetic methyl methacrylate (MMA). d Capture of chlorine radical species. e Key intermediates of this carbonylation. f S-(p-tolyl) benzenesulfonothioate experiment. a 1 mmol Scale-up carbonylation. b Added KOH (1 equiv.), MeOH (10 equiv.), r.t., 4 h.
