Table 1 Reaction Optimization^a


Entry	Variation from the standard conditions	Yield (%)^b
1	None	63
2	Fukuzumi dye instead of [Ir]	27
3	4CzIPN instead of [Ir]	36
4^c	AgNO₃ instead of [Ir]	20
5	Cs₂CO₃ instead of KHCO₃	22
6	K₂CO₃ instead of KHCO₃	28
7	MeCN instead of DCM	22
8	DMF instead of DCM	18
9	THF instead of DCM	25
10	Dioxane instead of DCM	15
11	in dark	Trace
12	without [Ir]	Trace
13	without KHCO₃	Trace
14	under air	Trace

^aStandard reaction conditions: 1a (0.1 mmol), 2a (0.2 mmol), [Ir(dF(CF₃)ppy)₂(dtbbpy)]PF₆ (2 mol %), Selectfluor (0.3 mmol), and KHCO₃ (0.3 mmol) in DCM (1 mL), irradiated with 30 W blue LEDs at 20 ^oC under N₂ for 48 h.
^bYield of isolated products.
^cAgNO₃ (30 mol %) was used without light irradiation.

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