Fig. 2: The detailed annotation of two-dimensional and three-dimensional interpenetration structure of SC-1. | Nature Communications

Fig. 2: The detailed annotation of two-dimensional and three-dimensional interpenetration structure of SC-1.

From: Photo-controlled vacancies and conductivity within single crystals of silver chalcogenolate cluster-based MOFs

Fig. 2

a The frame structure of SC-1 (the local magnification shows that there are two coordination modes in the interpenetration structure: Ag12 cluster is connected to 6 surrounding clusters to form a 3D frame and a Ag12 cluster is connected to 4 surrounding clusters to form a 2D network). b, c the coordination modes of TCNB in two-dimensional network and three-dimensional framework (the gray/shaded structure is located inside the plane to show its three-dimensional character). d, e 2D-3D frame topology and space-filling mode of SC-1. Color code: Ag12 cluster, light blue in 3D framework and orange in 2D-network; O, red; F, green C, gray and N, blue, the hydrogen atom is omitted for clarity.

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