Fig. 5: Working hypothesis of the selective hydrometallation and isomerization and proposed catalytic cycle. | Nature Communications

Fig. 5: Working hypothesis of the selective hydrometallation and isomerization and proposed catalytic cycle.

From: A contra-steric chemoselective hydrometallation strategy with bulky NHC for catalytic asymmetric branched allylamine synthesis

Fig. 5

a Hemilabile coordination effect on selective hydrometallation. b Hemilabile coordination effect on regio- & E-selective isomerization. c Proposed NHC-controlled cross-HA and 3 to 3' isomerization catalytic cycle illustrated by enamine 1 and α-olefin 2.

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