Fig. 1: Overview of established synthetic routes to polydithiocarbamates. | Nature Communications

Fig. 1: Overview of established synthetic routes to polydithiocarbamates.

From: N-alkylated polydithiocarbamates derived from thiocarbonyl fluoride as macro-photoiniferters for living 3D printing

Fig. 1

a Multicomponent polymerization of isocyanides, thiols, and elemental sulfur. b Polyaddition reaction between isocyanates and thiols. c Polymerization involving primary amines, acrylates, and carbon disulfide (CS2). d Synthesis of structurally specific N-alkylated polydithiocarbamates from activated internal alkynes, aliphatic secondary amines, and CS2. e A general synthesis of N-alkylated polydithiocarbamates using thiocarbonyl fluoride, secondary amines, and thiols.

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