Fig. 5: Cross-coupling reactions of aryl chlorides. | Nature Communications

Fig. 5: Cross-coupling reactions of aryl chlorides.

From: General method for carbon–heteroatom cross-coupling reactions via semiheterogeneous red-light metallaphotocatalysis

Fig. 5: Cross-coupling reactions of aryl chlorides.The alternative text for this image may have been generated using AI.

a Reaction conditions, unless otherwise noted: aryl chloride (0.2 mmol), NuH (0.4 mmol), CN-OA-m (10 mg mL−1), NiBr2·glyme (10.0 mol %), DMAc (1 mL), mDBU (1.5 equiv.), red light (660–670 nm), 85 °C, Ar, 36 h. b 48 h. c with d-tbbpy (10.0 mol%). d 620–630 nm, NuH (0.6 mmol). Isolated yields are provided. For details, see Supplementary Information.

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