Fig. 1: Synthesis, structure, and ground state properties of [Mn(pbmi)2][OTf].
From: A manganese(I) complex with a 190 ns metal-to-ligand charge transfer lifetime
![Fig. 1: Synthesis, structure, and ground state properties of [Mn(pbmi)2][OTf].](http://media.springernature.com/full/springer-static/image/art%3A10.1038%2Fs41467-025-63225-4/MediaObjects/41467_2025_63225_Fig1_HTML.png?as=webp)
a Synthesis of [Mn(pbmi)2][OTf] from Mn[OTf]2, excess pro-ligand [H2pbmi]Br2, and Na[N(SiMe3)2] in THF. b Molecular structure of the cation of [Mn(pbmi)2][OTf] determined by single-crystal X-ray diffraction (XRD), shown with thermal ellipsoids at the 50 % probability level and hydrogen atoms omitted for clarity. c Infrared (IR) (top) and Raman (bottom, excitation at 1064 nm) spectra of [Mn(pbmi)2][OTf] in the solid state. Asterisks denote bands of the counter ion. d Cyclic voltammogram of [Mn(pbmi)2][OTf] (1 mM) in CH3CN containing [nBu4N][PF6] (100 mM) as supporting electrolyte. Scan rate 100 mV s−1. Potentials are referenced vs SCE37.
