Fig. 3: Scope of terminal C–H functionalization of N-allylimine.
From: Bimetallic [Co/K] hydrogen evolution catalyst for electrochemical terminal C-H functionalization
Reaction conditions: 1 (1.5 mmol), 2 (0.5 mmol), cat 2 (5 mol%), nBu4NClO4 (1.0 mmol), DMF (10 mL), graphite felt anode, nickel plate cathode, undivided cell, CCE = 18 mA, 3 h (4.03 F/mol), 0 °C; Yields were based on isolated products; dr > 15/1, unless otherwise noted. aThe reaction is conducted on a 0.3 mmol scale. GF graphite felt, CCE constant current electrolysis, DMF N,N-dimethylformamide.
