Fig. 2: Rational design and optimization. Reaction condition.
From: Photochemical rearrangement of isonitriles via energy transfer catalysis
1a (0.2 mmol), Thioxanthone (TXT, 5 mol %), and MeCN (2 mL, 0.1 M) at room temperature under 30 W 405 nm LEDs with a cooling fan for 12 h under N2. a Isolated yield. b 450 nm LEDs are used instead of 405 nm LEDs. c PhCF3 as solvent. d Thioxanthone (TXT, 1 mol%) was used as photocatalyst.
