Fig. 1: Asymmetric synthesis of boron–stereogenic and C–B axially chiral compounds. | Nature Communications

Fig. 1: Asymmetric synthesis of boron–stereogenic and C–B axially chiral compounds.

From: Rhodium-catalyzed construction of boron-based point and axial chirality via asymmetric annulation of alkynylborons

Fig. 1: Asymmetric synthesis of boron–stereogenic and C–B axially chiral compounds.The alternative text for this image may have been generated using AI.

a Chiral organoboron compounds as natural products and materials. b Enantioselective synthesis of Boron-Stereogenic and C–B axially chiral compounds. c Asymmetric transformation of (hetero atom-functionalized) alkynes to construct centrally and axially chiral compounds. d Enantioselective annulation of diverse arenes with boron-alkynes: access to boron-stereogenic and C–B axially chiral cycles (this work).

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