Fig. 8: Probing the reductive N–O bond cleavage of isoxazolidine.
From: Harnessing nitroarenes as nitrogen and oxygen sources for general oxo-aminomethylation of alkenes
A Effect of protonation on the N–O bond cleavage of isoxazolidine. B Reactivity of the photocatalyst toward N–O bond cleavage of isoxazolidine. C Reactivity of the Ni–H species toward N–O bond cleavage of isoxazolidine. D Reactivity of the Ni0 species toward N–O bond cleavage of isoxazolidine. Me methyl, Cy cyclohexyl.
