Fig. 7: SANS characterisation of cylindrical and helical SPs.
From: Using in-situ small-angle scattering to reveal the structure and dynamics of supramolecular polymers
a Chemical structures of derivatives 7, 8 and 977,78. b (main panel) A plot of the length of the assembled structures estimated by SANS as a function of the fraction of 7. (Inset) SANS arising from mixtures of 7 and 8 as a function of the fraction of 7 (expressed as a %). c SANS data arising from a solution of 9 with n = 2 in deuterated dodecane (overall c = 0.5 wt%)77. (Main panel) Change in length and radii values obtained by SANS analysis as a function of fraction of 777. Reproduced from ref. 77 with permission from Springer Nature (c) (inset table) Comparison of the diameter of the helical/cylindrical structures obtained by molecular dynamics simulation (MD), SANS and atomic force microscopy (AFM)78. c (inset, top right corner) SP structure formed by 9 with n = 2, determined by MD simulations78. Reprinted with permission from ref. 78. Copyright 2003 American Chemical Society.
