Fig. 1: Stereogenic-at-sulfur compounds and methods for their synthesis. | Nature Communications

Fig. 1: Stereogenic-at-sulfur compounds and methods for their synthesis.

From: Asymmetric synthesis of stereogenic-at-sulfur compounds via biocatalytic oxidation with Unspecific Peroxygenases

Fig. 1: Stereogenic-at-sulfur compounds and methods for their synthesis.

a Examples of stereogenic-at-sulfur compounds used as pharmaceuticals, agrochemicals and in asymmetric synthesis/catalysis. b Wei and coworkers25: enantioselective synthesis of sulfinamides and sulfinate esters using bifunctional 4-arylpyridine N-oxide organocatalysts. c Robinson and coworkers33: sulfide to sulfoxide oxygenation using a UPO. d This work: enantioselective sulfoximine synthesis via the UPO catalysed oxygenation of sulfilimines, using a kinetic resolution approach. e This work: enantioselective synthesis of sulfinimine enantiomers via the UPO catalysed oxygenation of sulfenimines.

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