Fig. 1: The challenges posed by the scaling of Cu interconnect and the requirements for the materials available for the next-generation diffusion barrier.

a The schematic diagram representative of the damascene structure of Cu interconnect. b Comparison between the diffusion barrier fabricated in this work (Ru SA-rGO/SAM structure) and the conventional TaN/Ta bilayer. The diffusion barrier presented in this work simultaneously meets the requirements of ultra-thin, excellent diffusion barrier properties, high conductivity, and compatibility with BEOL process.