Fig. 3: Activation of methane and the evolution of H2O2 into ROS.

a EPR spectra of FeCu/ZSM-CI. b EPR spectra of FeCu/ZSM-CI under different reaction conditions. c Quenching experiments. d 1H-NMR spectrum of DMSO oxidation. e In situ CV tests of catalysts for H2O2 activation. f PL spectra of 7-hydroxycoumarin by •OH under different catalysts. g NBT degradation experiment spectra by •O2− under different catalysts. h The ratio of •O2− and •OH generated on FeCu/ZSM-CI. i Decomposition pathways of H2O2 at FeCu/ZSM-CI metal sites.