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Non-toxic silver telluride colloidal quantum dot mid-infrared photodetector
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  • Published: 04 April 2026

Non-toxic silver telluride colloidal quantum dot mid-infrared photodetector

  • So Young Eom1 na1,
  • Jin Hyeok Lee1 na1,
  • Haemin Song1,
  • Suheon Son1 &
  • …
  • Kwang Seob Jeong  ORCID: orcid.org/0000-0003-3246-75991 

Nature Communications , Article number:  (2026) Cite this article

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We are providing an unedited version of this manuscript to give early access to its findings. Before final publication, the manuscript will undergo further editing. Please note there may be errors present which affect the content, and all legal disclaimers apply.

Subjects

  • Electronic materials
  • Mid-infrared photonics
  • Quantum dots
  • Sensors and biosensors

Abstract

As demand for sustainable and biocompatible technologies grows, low-toxicity mid-infrared materials, such as silver chalcogenides, have attracted significant interest. Herein, we report mid-wavelength infrared tunable Ag2Te colloidal quantum dots through a post-growth method starting from short-wavelength infrared Ag2Te colloidal quantum dots. Using the synthesized Ag2Te colloidal quantum dots, we successfully fabricate a photodetector covering the full mid-wavelength infrared spectral range (3–5 μm) with an onset wavelength extending to 6.9 μm. At 78 K, the photodetectors exhibit a photoresponse time of 230 ns (rise) and 576 ns (fall). Responsivity varies from 1.9 × 10-3 A W−1 at 0.02 V to 1.1 A W−1 at 0.5 V, depending on the applied bias, and the specific detectivity of the device is 1.2 × 109 Jones at 0.02 V. The measured noise-equivalent temperature difference of 0.3 K enables us to reliably distinguish temperature variations between 37 °C and 40 °C, directly enabling the diagnosis of fever-level body temperatures.

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Data availability

All data supporting the findings of this study are available within the paper and its Supplementary Information. Additional experimental data available from the corresponding author upon request.

References

  1. Sergeeva, K. A. et al. The rise of HgTe colloidal quantum dots for infrared optoelectronics. Adv. Funct. Mater. 34, 2405307 (2024).

    Google Scholar 

  2. Itsuno, A. M., Phillips, J. D. & Velicu, S. Mid-wave infrared HgCdTe nBn photodetector. Appl. Phys. Lett. 100, 161102 (2012).

    Google Scholar 

  3. Kovalenko, M. V. et al. Colloidal HgTe nanocrystals with widely tunable narrow band gap energies: from telecommunications to molecular vibrations. J. Am. Chem. Soc. 128, 3516–3517 (2006).

    Google Scholar 

  4. Guo, Q. et al. Black phosphorus mid-infrared photodetectors with high gain. Nano Lett. 16, 4648–4655 (2016).

    Google Scholar 

  5. Xue, X. et al. High-operating-temperature mid-infrared photodetectors via quantum dot gradient homojunction. Light Sci. Appl. 12, 2 (2023).

    Google Scholar 

  6. Mu, G. et al. Visible to mid-wave infrared PbS/HgTe colloidal quantum dot imagers. Nat. Photon. 18, 1147–1154 (2024).

    Google Scholar 

  7. Peterson, J. C. & Guyot-Sionnest, P. Room-temperature 15% efficient mid-infrared HgTe colloidal quantum dot photodiodes. ACS Appl. Mater. Interfaces 15, 19163–19169 (2023).

    Google Scholar 

  8. Song, H. et al. Narrow bandgap silver mercury telluride alloy semiconductor nanocrystal for self-powered midwavelength-infrared photodiode. Commun. Mater. 5, 60 (2024).

    Google Scholar 

  9. Zhang, S. et al. Spray-stencil lithography enabled large-scale fabrication of multispectral colloidal quantum-dot infrared detectors. Adv. Mater. Technol. 7, 2101132 (2022).

    Google Scholar 

  10. Zhang, H. et al. Material perspective on HgTe nanocrystal-based short-wave infrared focal plane arrays. Chem. Mater. 34, 10964–10972 (2022).

    Google Scholar 

  11. Zhang, S. et al. Direct optical lithography enabled multispectral colloidal quantum-dot imagers from ultraviolet to short-wave infrared. ACS Nano 16, 18822–18829 (2022).

    Google Scholar 

  12. Yang, J. et al. Ligand-engineered HgTe colloidal quantum dot solids for infrared photodetectors. Nano Lett. 22, 3465–3472 (2022).

    Google Scholar 

  13. Lhuillier, E. et al. Infrared photodetection based on colloidal quantum-dot films with high mobility and optical absorption up to THz. Nano Lett. 16, 1282–1286 (2016).

    Google Scholar 

  14. Park, M., Choi, D., Choi, Y., Shin, H. & Jeong, K. S. Mid-Infrared intraband transition of metal excess colloidal Ag 2 Se nanocrystals. ACS Photonics 5, 1907–1911 (2018).

    Google Scholar 

  15. Kim, G., Choi, D., Eom, S. Y., Song, H. & Jeong, K. S. Extended short-wavelength infrared photoluminescence and photocurrent of nonstoichiometric silver telluride colloidal nanocrystals. Nano Lett. 21, 8073–8079 (2021).

    Google Scholar 

  16. Son, J., Choi, D., Park, M., Kim, J. & Jeong, K. S. Transformation of colloidal quantum dot: from intraband transition to localized surface plasmon resonance. Nano Lett. 20, 4985–4992 (2020).

    Google Scholar 

  17. Ansari, S., Bianconi, S., Kang, C. & Mohseni, H. From material to cameras: low-dimensional photodetector arrays on CMOS. Small Methods 8, 2300595 (2024).

    Google Scholar 

  18. Zhang, H. et al. Infrared imaging using thermally stable HgTe/CdS nanocrystals. Nano Lett. 24, 5039-5046 (2024).

  19. Luo, Y. et al. Megapixel large-format colloidal quantum-dot infrared imagers with resonant-cavity enhanced photoresponse. APL Photonics 8, 056109 (2023).

    Google Scholar 

  20. Mu, G., Lin, Y., Fu, K. & Tang, X. Infrared visualized snakes-inspired artificial vision systems with CMOS sensors-integrated upconverters. Light Sci. Appl 14, 282 (2025).

    Google Scholar 

  21. Bera, R., Choi, D., Jung, Y. S., Song, H. & Jeong, K. S. Intraband transitions of nanocrystals transforming from lead selenide to self-doped silver selenide quantum dots by cation exchange. J. Phys. Chem. Lett. 13, 6138–6146 (2022).

    Google Scholar 

  22. Deng, Z., Jeong, K. S. & Guyot-Sionnest, P. Colloidal quantum dots intraband photodetectors. ACS Nano 8, 11707–11714 (2014).

    Google Scholar 

  23. Zhang, H., Peterson, J. C. & Guyot-Sionnest, P. Intraband transition of HgTe nanocrystals for long-wave infrared detection at 12 μm. ACS Nano 17, 7530–7538 (2023).

    Google Scholar 

  24. Xue, X., Hao, Q. & Chen, M. Very long wave infrared quantum dot photodetector up to 18 μm. Light Sci. Appl. 13, 89 (2024).

    Google Scholar 

  25. Wang, Y. et al. Silver telluride colloidal quantum dot infrared photodetectors and image sensors. Nat. Photon. 18, 236–242 (2024).

    Google Scholar 

  26. Kim, G. et al. Extended short-wavelength infrared ink by surface-tuned silver telluride colloidal quantum dots and their infrared photodetection. ACS Mater. Lett. 6, 4988–4996 (2024).

    Google Scholar 

  27. Ahn, Y. et al. Silver telluride colloidal quantum dot solid for fast extended shortwave infrared photodetector. Adv. Sci. 11, 2407453 (2024).

    Google Scholar 

  28. Wang, Y. et al. Shortwave infrared light detection and ranging using silver telluride quantum dots. Adv. Mater. 37, 2500977 (2025).

    Google Scholar 

  29. Voorhees, P. W. The theory of Ostwald ripening. J. Stat. Phys. 38, 231–252 (1985).

    Google Scholar 

  30. Lifshitz, I. M. & Slyozov, V. V. The kinetics of precipitation from supersaturated solid solutions. J. Phys. Chem. Solids 19, 35–50 (1961).

    Google Scholar 

  31. Joo, J. et al. A reduction pathway in the synthesis of PbSe nanocrystal quantum dots. J. Am. Chem. Soc. 131, 10620–10628 (2009).

    Google Scholar 

  32. Sahu, A., Qi, L., Kang, M. S., Deng, D. & Norris, D. J. Facile synthesis of silver chalcogenide (Ag 2 E; E = Se, S, Te) semiconductor nanocrystals. J. Am. Chem. Soc. 133, 6509–6512 (2011).

    Google Scholar 

  33. Aharoni, A., Oron, D., Banin, U., Rabani, E. & Jortner, J. Long-range electronic-to-vibrational energy transfer from nanocrystals to their surrounding matrix environment. Phys. Rev. Lett. 100, 057404 (2008).

    Google Scholar 

  34. Liu, H., Pourret, A. & Guyot-Sionnest, P. Mott and Efros-Shklovskii variable range hopping in CdSe quantum dot films. ACS Nano 4, 5211–5216 (2010).

    Google Scholar 

  35. Berends, A. C. et al. Radiative and nonradiative recombination in CuInS2 nanocrystals and CuInS2 -based core/shell nanocrystals. J. Phys. Chem. Lett. 7, 3503–3509 (2016).

    Google Scholar 

  36. Kennehan, E. R. et al. Electron–phonon coupling and resonant relaxation from 1D and 1P states in PbS quantum dots. ACS Nano 12, 6263–6272 (2018).

    Google Scholar 

  37. Konstantatos, G. & Sargent, E. H. PbS colloidal quantum dot photoconductive photodetectors: Transport, traps, and gain. Appl. Phys. Lett. 91, 173505 (2007).

    Google Scholar 

  38. Balazs, D. M. et al. Stoichiometric control of the density of states in PbS colloidal quantum dot solids. Sci. Adv. 3, eaao1558 (2017).

    Google Scholar 

  39. Kang, M. S., Sahu, A., Norris, D. J. & Frisbie, C. D. Size- and temperature-dependent charge transport in PbSe nanocrystal thin films. Nano Lett. 11, 3887–3892 (2011).

    Google Scholar 

  40. Miller, A. & Abrahams, E. Impurity conduction at low concentrations. Phys. Rev. 120, 745–755 (1960).

    Google Scholar 

  41. Emin, D. Phonon-assisted jump rate in noncrystalline solids. Phys. Rev. Lett. 32, 303–307 (1974).

    Google Scholar 

  42. Keuleyan, S., Lhuillier, E., Brajuskovic, V. & Guyot-Sionnest, P. Mid-infrared HgTe colloidal quantum dot photodetectors. Nat. Photon 5, 489–493 (2011).

    Google Scholar 

Download references

Acknowledgments

This research was supported by the Basic Science Research Program (NR059609 and NR068167) (K.S.J.). This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (RS-2025-25437404 and RS-2024-00407943) (S.Y.E. and H.S).

Author information

Author notes
  1. These authors contributed equally: So Young Eom, Jin Hyeok Lee.

Authors and Affiliations

  1. Department of Chemistry, Korea University, Seoul, Republic of Korea

    So Young Eom, Jin Hyeok Lee, Haemin Song, Suheon Son & Kwang Seob Jeong

Authors
  1. So Young Eom
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  2. Jin Hyeok Lee
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Contributions

S.Y.E. developed Ag2Te QD synthesis methods. J.H.L. carried out the temperature-dependent infrared photoluminescence and photocurrent spectroscopy measurement. S.Y.E. and J.H.L. infrared photodetection measurements and analysis. S.S. assisted in synthesizing the QD. H.S. assisted in infrared photodetection. S.Y.E., J.H.L., and K.S.J. wrote the manuscript with contributions from all co-authors, and K.S.J. supervised the project. All authors contributed to the discussion of the experimental results and the manuscript.

Corresponding author

Correspondence to Kwang Seob Jeong.

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Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Cite this article

Eom, S.Y., Lee, J.H., Song, H. et al. Non-toxic silver telluride colloidal quantum dot mid-infrared photodetector. Nat Commun (2026). https://doi.org/10.1038/s41467-026-71374-3

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  • Received: 14 November 2025

  • Accepted: 23 March 2026

  • Published: 04 April 2026

  • DOI: https://doi.org/10.1038/s41467-026-71374-3

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