Abstract
Superconductivity is observed in rhombohedral trilayer graphene in a narrow regime between the flavour-symmetric state and the symmetry breaking phase, which cannot be described by the conventional Bardeen-Cooper-Schrieffer theory. The measured coherence length, for instance, is roughly two orders of magnitude shorter than the value predicted by the Bardeen-Cooper-Schrieffer relation based on the large fermi velocity and an extremely low charge carrier density of the flavour-symmetric phase. To resolve the discrepancies, we propose that the rhombohedral trilayer graphene superconducting phase arises from the pairing of quasiparticles of the adjacent inter-valley coherent state. We illustrate the superconducting phenomenology using gapped Dirac cones with the chemical potential μ close to the valence band’s edge. Our findings indicate that the transition temperature Tc obeys \({T}_{c}\propto {\epsilon }_{D}\exp (-2/{\rho }_{\rm{qp}}U)\) with the density of states ρqp of intervalley coherent state quasiparticles, which is much suppressed compared to predictions from the Bardeen-Cooper-Schrieffer theory. The coherence length ξ we predict behaves according to \(\xi \sim v/\sqrt{\mu {T}_{c}}\) with v being the velocity of Dirac cone. Applying our assumption to a microscopic model, our predictions align well with experimental data and effectively capture key measurable quantities such as the transition temperature Tc and the coherence length ξ `without parameter fine-tuning.
Acknowledgements
C.W.C. acknowledges funding from the Croucher Cambridge International Scholarship by the Croucher Foundation and the Cambridge Trust. K. T. L. acknowledges the support of the Ministry of Science and Technology, China, The New Cornerstone Foundation, and the Hong Kong Research Grants Council through Grants No. MOST23SC01-A, No. RFS2021-6S03, No. C6053-23G, No. AoE/P-701/20, AoE/P-604/25R, No. 16309223, No. 16311424 and No. 16300325.
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Chau, C.W., Chen, S.A. & Law, K.T. Superconductivity from quasiparticle pairing of intervalley coherent state in rhombohedral trilayer graphene. Nat Commun (2026). https://doi.org/10.1038/s41467-026-72135-y
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DOI: https://doi.org/10.1038/s41467-026-72135-y