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Superconductivity from quasiparticle pairing of intervalley coherent state in rhombohedral trilayer graphene
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  • Published: 28 May 2026

Superconductivity from quasiparticle pairing of intervalley coherent state in rhombohedral trilayer graphene

  • Chun Wang Chau  ORCID: orcid.org/0009-0000-8246-90531,2,
  • Shuai A. Chen  ORCID: orcid.org/0000-0002-8996-75031,3 &
  • K. T. Law  ORCID: orcid.org/0000-0003-0501-62901 

Nature Communications (2026) Cite this article

We are providing an unedited version of this manuscript to give early access to its findings. Before final publication, the manuscript will undergo further editing. Please note there may be errors present which affect the content, and all legal disclaimers apply.

Subjects

  • Electronic properties and materials
  • Superconducting properties and materials

Abstract

Superconductivity is observed in rhombohedral trilayer graphene in a narrow regime between the flavour-symmetric state and the symmetry breaking phase, which cannot be described by the conventional Bardeen-Cooper-Schrieffer theory. The measured coherence length, for instance, is roughly two orders of magnitude shorter than the value predicted by the Bardeen-Cooper-Schrieffer relation based on the large fermi velocity and an extremely low charge carrier density of the flavour-symmetric phase. To resolve the discrepancies, we propose that the rhombohedral trilayer graphene superconducting phase arises from the pairing of quasiparticles of the adjacent inter-valley coherent state. We illustrate the superconducting phenomenology using gapped Dirac cones with the chemical potential μ close to the valence band’s edge. Our findings indicate that the transition temperature Tc obeys \({T}_{c}\propto {\epsilon }_{D}\exp (-2/{\rho }_{\rm{qp}}U)\) with the density of states ρqp of intervalley coherent state quasiparticles, which is much suppressed compared to predictions from the Bardeen-Cooper-Schrieffer theory. The coherence length ξ we predict behaves according to \(\xi \sim v/\sqrt{\mu {T}_{c}}\) with v being the velocity of Dirac cone. Applying our assumption to a microscopic model, our predictions align well with experimental data and effectively capture key measurable quantities such as the transition temperature Tc and the coherence length ξ `without parameter fine-tuning.

Acknowledgements

C.W.C. acknowledges funding from the Croucher Cambridge International Scholarship by the Croucher Foundation and the Cambridge Trust. K. T. L. acknowledges the support of the Ministry of Science and Technology, China, The New Cornerstone Foundation, and the Hong Kong Research Grants Council through Grants No. MOST23SC01-A, No. RFS2021-6S03, No. C6053-23G, No. AoE/P-701/20, AoE/P-604/25R, No. 16309223, No. 16311424 and No. 16300325.

Funding

Open Access funding enabled and organized by Projekt DEAL.

Author information

Authors and Affiliations

  1. Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong, China

    Chun Wang Chau, Shuai A. Chen & K. T. Law

  2. Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, Cambridge, UK

    Chun Wang Chau

  3. Max Planck Institute for the Physics of Complex Systems, 01187, Dresden, Germany

    Shuai A. Chen

Authors
  1. Chun Wang Chau
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  2. Shuai A. Chen
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  3. K. T. Law
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Corresponding authors

Correspondence to Shuai A. Chen or K. T. Law.

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Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

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Cite this article

Chau, C.W., Chen, S.A. & Law, K.T. Superconductivity from quasiparticle pairing of intervalley coherent state in rhombohedral trilayer graphene. Nat Commun (2026). https://doi.org/10.1038/s41467-026-72135-y

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  • Received: 11 March 2025

  • Accepted: 07 April 2026

  • Published: 28 May 2026

  • DOI: https://doi.org/10.1038/s41467-026-72135-y

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