Table 4 Cu(I) oxidation reactions and kinetic constants

From: Oxic corrosion model for KAERI Reference disposal system via O2 consumption reactions and mixed-potential theory

Reaction

kf (m3∙mol-1 ∙ s-1)

\(C{u}^{+}+{O}_{2}\to {Cu}({II})\)

3.1E4

\({CuClO}{H}^{-}+{O}_{2}\to {Cu}({II})\)

3.1E2

\({CuCl}+{O}_{2}\to {Cu}({II})\)

1.9E1

\({CuC}{l}_{3}^{-2}+{O}_{2}\to {Cu}({II})\)

4.4E-1

\({CuC}{l}_{2}^{-}+{O}_{2}\to {Cu}({II})\)

1.2E-1

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