Extended Data Fig. 5: Lattice structures of NOICs with symmetric TATAs.
From: Self-assembly of chiroptical ionic co-crystals from silver nanoclusters and organic macrocycles
Structures of a, NOIC25−3C6‒L/R, b, NOIC25−3C7‒L/R and c, NOIC25−3C8‒L/R. In TATA3C8+ (panel c), the three C8 chains are disordered among three conformations (marked in different colors) with occupancies of each disorder type = 0.33 for NOIC25−3C8‒L; the C5‒C8 atoms of the three C8 chains (highlighted in orange) are disordered between two conformations with occupancies of both disorder type I/II = 0.5(3) for NOIC25−3C8‒R. Color codes: light blue = N, blue/magenta/yellow/orange/pink = C in TATA+; purple = Ag, yellow = S, grey = C. Note that H atoms and CH2Cl2 solvent molecules in the crystal structures are omitted for clarity.
