Abstract
The superconducting diode is a device that allows supercurrent to flow in one direction but not the other. Usually, the state that does not allow supercurrent has no Cooper pairs. Here we report a quantized version of the superconducting diode that operates solely between Cooper-paired states. This type of quantum superconducting diode takes advantage of quantized Shapiro steps for digitized output. The device consists of twisted high-temperature cuprate superconductors and exhibits the following characteristics. First, we show that a non-reciprocal diode behaviour can be initiated by training with current pulses without applying an external magnetic field. Then, we demonstrate perfect diode efficiency under microwave irradiation above liquid-nitrogen temperature. Lastly, the quantized nature of the output offers high resilience against input noise. These features open up opportunities to develop practical dissipationless quantum circuits.
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Acknowledgements
We thank G. Gu for providing us with the Bi2212 crystals. This work is financially supported by the Ministry of Science and Technology of China (grant no. 2022YFA1403100 (D.Z. and Q.-K.X.)); the National Natural Science Foundation of China (grant nos. 12141402 (Y.Z.), 52388201 (D.Z. and Q.-K.X.), 12361141820 (D.Z.), 12274249 (D.Z.) and T2425009 (D.Z.)); Innovation Program for Quantum Science and Technology (grant nos. 2021ZD0302600 (Y.Z. and Z.L.) and 2021ZD0302400 (D.Z.)); and the China Postdoctoral Science Foundation (grant nos. GZB20240294 (H.W.) and 2024M751287 (H.W.)).
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H.W. and Y.Z. fabricated the devices. H.W., Y.Z. and D.Z. carried out the transport measurements with technical assistance from Z.L. J.Y., L.Z. and X.J.Z. grew the single crystals. H.W. carried out the theoretical modelling. H.W., Y.Z., D.Z. and Q.-K.X. analysed the data and wrote the paper with the input from Z.B. All authors discussed the results and commented on the manuscript.
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Wang, H., Zhu, Y., Bai, Z. et al. Quantum superconducting diode effect with perfect efficiency above liquid-nitrogen temperature. Nat. Phys. 22, 47–53 (2026). https://doi.org/10.1038/s41567-025-03098-y
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DOI: https://doi.org/10.1038/s41567-025-03098-y


