Fig. 2: Scope for the deaminative arylation.
From: Deaminative cross-coupling of amines by boryl radical β-scission
a, Evaluation of amines 1a–1v in the cross-coupling with Ph–B(OH)2. b, Scope of boronic acids in the deaminative cross-coupling with 1d. ‡Reaction run with amine (2.0 equiv.), Ph–B(OH)2 (1.0 equiv.), 2.5 mol% [Cu] and 3 mol% bathophen. *Reaction run with 2.5 mol% [Cu] and 3 mol% bathophen. †Acetone was used as solvent. Ar, p-TBSO-C6H4; r.t., room temperature.
