Table 2 13C NMR Spectroscopic Data for Compounds 1–16 (δ in ppm).
No. | 1a | 2a | 3b | 4a | 5b | 6a | 7a | 8a | 9b | 10a | 11a | 12b | 13a | 14a | 15b | 16b |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 48.8 | 48.8 | 48.9 | 48.8 | 49.1 | 49.2 | 48.9 | 43.9 | 43.9 | 43.9 | 43.9 | 43.8 | 43.9 | 43.9 | 25.7 | 25.4 |
2 | 70.9 | 70.8 | 70.9 | 70.8 | 71.0 | 70.8 | 70.9 | 73.7 | 73.7 | 73.8 | 73.7 | 73.7 | 73.7 | 73.7 | 33.0 | 33.2 |
3 | 40.4 | 40.5 | 40.5 | 40.5 | 40.5 | 40.5 | 40.6 | 37.1 | 37.1 | 37.3 | 37.3 | 37.1 | 37.3 | 37.3 | 217.9 | 217.8 |
4 | 43.4 | 43.3 | 43.4 | 43.3 | 43.5 | 43.4 | 43.4 | 35.9 | 36.0 | 35.9 | 35.9 | 35.8 | 35.9 | 35.9 | 80.4 | 80.4 |
5 | 105.6 | 105.7 | 105.7 | 105.7 | 105.7 | 105.7 | 105.7 | 105.6 | 105.6 | 105.8 | 105.8 | 105.6 | 105.8 | 105.8 | 78.1 | 78.1 |
6 | 74.4 | 74.3 | 74.7 | 74.4 | 74.5 | 74.4 | 74.4 | 75.6 | 75.6 | 75.8 | 75.8 | 75.7 | 75.8 | 75.8 | 80.0 | 80.0 |
7 | 45.9 | 45.8 | 45.8 | 45.8 | 45.9 | 45.8 | 45.8 | 44.9 | 44.9 | 45.1 | 45.1 | 45.0 | 45.0 | 45.1 | 41.7 | 41.6 |
8 | 78.1 | 78.1 | 78.1 | 78.1 | 78.2 | 78.2 | 78.2 | 78.1 | 78.0 | 78.2 | 78.1 | 78.2 | 78.3 | 78.2 | 70.5 | 70.3 |
9 | 80.3 | 80.4 | 80.3 | 80.3 | 80.5 | 80.5 | 80.4 | 78.0 | 77.9 | 78.0 | 77.9 | 77.8 | 78.0 | 78.0 | 78.5 | 78.7 |
10 | 72.0 | 72.0 | 72.1 | 72.1 | 72.1 | 72.1 | 72.2 | 71.2 | 71.3 | 71.1 | 71.3 | 71.1 | 71.1 | 71.2 | 30.1 | 29.9 |
11 | 134.8 | 135.0 | 134.9 | 135.0 | 135.0 | 135.0 | 135.1 | 134.4 | 134.4 | 134.6 | 134.7 | 134.5 | 134.6 | 134.6 | 132.8 | 132.8 |
12 | 170.2 | 170.3 | 170.3 | 170.3 | 170.3 | 170.3 | 170.2 | 169.9 | 169.8 | 169.9 | 169.9 | 169.9 | 170.0 | 170.0 | 169.7 | 169.7 |
13 | 124.2 | 124.3 | 124.3 | 124.3 | 124.3 | 124.3 | 124.3 | 125.6 | 125.4 | 125.5 | 125.4 | 125.4 | 125.5 | 125.6 | 124.0 | 123.9 |
14 | 23.3 | 23.3 | 23.3 | 23.3 | 23.5 | 23.4 | 23.4 | 29.2 | 29.3 | 29.4 | 29.3 | 29.2 | 29.2 | 29.2 | 20.0 | 20.0 |
15 | 12.5 | 12.3 | 12.1 | 12.3 | 12.6 | 12.3 | 12.4 | 13.6 | 13.6 | 13.6 | 13.6 | 13.5 | 13.6 | 13.6 | 23.4 | 23.4 |
1′ | 176.6 | 166.7 | 167.0 | 166.7 | 176.6 | 166.7 | 166.8 | 176.1 | 176.1 | 166.3 | 166.3 | 166.2 | 166.4 | 166.4 | 167.1 | 167.1 |
2′ | 33.9 | 127.1 | 128.0 | 127.1 | 33.9 | 127.1 | 127.1 | 33.8 | 33.8 | 127.1 | 127.1 | 127.0 | 127.1 | 127.1 | 127.5 | 127.5 |
3′ | 18.0 | 140.4 | 139.2 | 140.3 | 18.1 | 140.4 | 140.4 | 18.0 | 18.0 | 139.4 | 139.4 | 139.3 | 139.4 | 139.4 | 138.4 | 138.4 |
4′ | 17.7 | 19.1 | 13.2 | 19.1 | 17.6 | 19.2 | 19.1 | 17.8 | 17.8 | 19.2 | 19.3 | 19.1 | 19.2 | 19.3 | 19.3 | 19.3 |
5′ | 14.7 | 10.6 | 14.7 | 14.7 | 14.7 | 14.6 | 14.6 | 14.5 | 14.6 | 14.6 | 14.6 | 14.6 | ||||
1″ | 178.0 | 173.9 | 178.1 | 178.0 | 168.8 | 168.8 | 177.6 | 177.0 | 176.6 | 176.7 | 176.7 | 167.6 | 173.1 | 177.1 | 167.7 | 173.2 |
2″ | 33.5 | 42.2 | 33.5 | 33.5 | 127.8 | 127.8 | 41.0 | 33.8 | 41.1 | 41.4 | 41.1 | 127.7 | 42.6 | 33.8 | 127.8 | 43.2 |
3″ | 18.0 | 25.2 | 18.1 | 18.0 | 137.0 | 136.9 | 26.2 | 18.0 | 26.3 | 26.2 | 26.3 | 137.3 | 25.1 | 18.0 | 137.7 | 25.4 |
4″ | 17.9 | 21.4 | 18.0 | 17.9 | 19.3 | 19.1 | 15.9 | 17.8 | 15.7 | 16.0 | 15.7 | 19.1 | 21.4 | 17.8 | 19.5 | 21.4 |
5″ | 21.4 | 14.5 | 14.4 | 10.8 | 10.6 | 10.7 | 10.7 | 14.4 | 21.4 | 14.7 | 21.5 |
