Table 3 Chemical composition of the extract of H. perforatum calli obtained from field grown plants after treatment with perlite NPs and TiO2/perlite NCs.
Compunds | Peak area % | Classification | RT | RI | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Control | P 25 (mg/L) | P 50 (mg/L) | P 100 (mg/L) | P 150 (mg/L) | P 200 (mg/L) | P + T 25 (mg/L) | P + T 50 (mg/L) | P + T 100 (mg/L) | P + T 150 (mg/L) | P + T 200 (mg/L) | ||||
Pentadecane | — | — | — | 4.75 | — | — | — | — | — | — | — | Hydrocarbon-alkan | 17.91 | 1479 |
Hexadecane | — | — | — | 7.31 | — | — | — | — | — | — | — | Hydrocarbon-alkan | 20.6 | 1584 |
2-Benzyl-1,2,3,4-tetrahydro-1-phenethylidene-.beta.-carboline | — | — | — | 2.53 | — | — | — | — | — | — | — | Alkaloid | 20.86 | 1593 |
Heptadecane | — | — | — | 8.04 | — | — | — | — | — | — | — | Hydrocarbon—alkan | 23 | 1689 |
Octadecane | — | — | — | 10.54 | — | — | — | — | — | — | — | Hydrocarbon—alkan | 24.9 | 1788 |
Nonadecane | — | — | — | 10.9 | — | — | — | — | — | — | — | Hydrocarbon—alkan | 26.6 | 1887 |
Hexadecanoic acid, methyl ester (CAS) | — | — | — | 14.34 | — | — | — | — | — | — | — | Fatty acid | 27.2 | 1924 |
3,11—diheptyloxybenzo[c]benzo[a]phenanthrene | — | 2.27 | — | 3.38 | — | — | — | — | — | — | — | Phenolic | 27.8 | 1963 |
Eicosane | — | — | — | 11.57 | — | — | — | — | — | — | — | Hydrocarbon—alkan | 28.22 | 1991 |
7-Acetoxyeicosane | — | — | — | 5.21 | — | — | — | — | — | — | — | Ester | 28.58 | 2015 |
Heneicosane | — | — | — | 8.07 | — | — | — | — | — | — | — | Hydrocarbon—alkan | 29.7 | 2090 |
Octadecane, 3-ethyl-5-(2-ethylbutyl)- | 0.5 | 2.27 | — | — | — | — | — | — | — | — | — | Hydrocarbon | 35.2 | 2296 |
Tetracosane | — | — | — | 2.07 | — | — | — | — | — | — | — | Hydrocarbon-alkan | 35.28 | 2401 |
Hexadecane, 8-hexyl-8-pentyl | — | 6.82 | — | — | — | — | — | — | — | — | Hydrocarbon-alkan | 35.64 | 2425 | |
Pentacosane | — | — | — | 3.35 | — | — | — | — | — | — | — | Hydrocarbon-alkan | 36.8 | 2501 |
1,2-Benzenedicarboxylic acid, ditridecyl ester | — | — | — | 7.1 | — | — | — | — | — | — | — | Acid | 37.49 | 2553 |
(Z,Z)-4-Ethyl-3-methyl-5-(5-4-aminophenyl-2-methylen)-3,4-dimethyl-5H-pyrrolyl-2-methylene)-3-pyrrolin-2-on | — | — | — | — | — | 3.8 | — | — | — | — | — | Alkaloid | 37.7 | 2568 |
phenaleno[3,2-f]quinolin-7-one | — | — | — | — | — | — | — | — | — | 12.14 | — | Alkaloid | 39.21 | 2686 |
2,2,3,3-TETRAFLUORO-5-(1,1,2,2-TETRAFLUOROETHOXY)-2,3-DIHYDROBENZOFURANOBENZOFURAN | 4.81 | 15.91 | 3.81 | - | 16.06 | — | 2.56 | 0.89 | — | 12.86 | — | Phenolic | 39.41 | 2703 |
6H-phenanthro[9,8-gh]quinolin-6-one | — | — | 5.71 | — | — | — | — | 1.53 | — | — | — | Alkaloid | 39.7 | 2728 |
(S)-(E)-(-)-4-Acetoxy-1-phenyl-2-dodecen-1-one | — | — | — | — | — | 2.38 | — | — | — | — | — | Ester | 40.19 | 2770 |
1,2-Benzenediol, 3,5-bis(1,1-dimethylethyl)- | — | — | — | — | — | — | — | — | — | — | 8.82 | Phenolic | 40.24 | 2775 |
5-Methylthio-7,8-dihydro-6H-benzocyclohepta[2,1-e]pyrazolo[1,5-a]pyrimidine | 9.45 | — | — | — | 15.03 | — | — | — | — | — | — | Alkaloid | 40.29 | 2779 |
Cyclohexane-1,3-dione, 2-allylaminomethylene-5,5-dimethyl | — | — | — | — | 6.74 | — | 6.11 | — | — | — | — | Hydrocarbon-alkan | 40.5 | 2797 |
1,2,4-Benzenetricarboxylic acid, 4-dodecyl dimethyl ester | 1.99 | 27.27 | — | — | — | — | — | 11.32 | — | — | — | Carboxylic acid | 40.59 | — |
4-Methoxy-3-(3-methoxyphenyl)-4-methylpentan-1-ol | — | — | — | — | — | — | — | 2.29 | — | — | — | Alcohol | 40.8 | — |
1,4-Phthalazinedione, 2,3-dihydro-6-nitro | 30.51 | 11.36 | — | — | — | 5.94 | 53.65 | — | — | 30.71 | — | Alkaloid | 41.37 | — |
Benzo[h]quinoline, 2,4-dimethyl- | 3.48 | — | — | — | — | — | 4.73 | — | 2.6 | — | — | Alkaloid | 41.4 | — |
7H-Dibenzo[b,g]carbazole, 7-methyl | — | — | 33.4 | — | — | — | — | — | — | — | — | Alkaloid | 41.5 | — |
6-methylthio[1]benzothieno[2,3-c]quinoline | — | — | 37 | — | — | — | — | — | — | — | — | Alkaloid | 42.07 | — |
2-(Acetoxymethyl)-3-(methoxycarbonyl)biphenylene | 15.26 | — | — | — | — | 52.97 | 26.23 | 52.29 | 79.69 | — | — | Aromatic | 43 | — |
Cyclopentanecarboxamide, 3-ethenyl-2-(3-pentenylidene)-N-phenyl-, [1.alpha.,2Z(E),3.alpha.]- | 18.57 | 27.27 | — | — | 38 | 26.13 | — | 24.81 | — | 17.86 | 42.65 | Aromatic | 43.55 | — |
Total identification | 84.57 | 70.88 | 79.92 | 92.06 | 89.82 | 91.22 | 93.29 | 83.21 | 82.29 | 73.57 | 51.47 | |||
Fatty acids | — | — | — | 14.34 | — | — | — | — | — | — | — | |||
Hydrocarbons-aliphatic | 0.5 | 13.64 | — | 66.6 | 3.8 | — | — | 1.4 | — | — | — | |||
Hydrocarbons-aromatic | 33.83 | 25 | — | — | 48.19 | 79.1 | 26.23 | 77.1 | 79.69 | 17.86 | 42.65 | |||
Operating agant hydrocarbon | — | 2.27 | — | 5.21 | 6.74 | 2.38 | 6.11 | 2.29 | — | — | — | |||
Alkaloids | 43.44 | 11.36 | 76.11 | 2.53 | 15.03 | 9.74 | 58.38 | 1.53 | 2.6 | 42.85 | — | |||
Phenolic compounds | 4.81 | 18.61 | 3.81 | 3.38 | 16.06 | — | 2.57 | 0.89 | — | 12.86 | 8.82 | |||
sesquiterpenes | — | — | — | — | — | — | — | — | — | — | — | |||
Steroids | — | — | — | — | — | — | — | — | — | — | — | |||
Carboxylic acid | 1.99 | — | — | 7.1 | — | — | — | 11.32 | — | — | — | |||
diterpenes | — | — | — | — | — | — | — | — | — | — | — | |||
