Scientific Reports

Table 10 Values of \({\gamma }_{s}^{d}\) of different catalysts as a function of temperature, rhodium percentage and molecular model using the straight-line method.

From: New approach to determine the surface and interface thermodynamic properties of H-β-zeolite/rhodium catalysts by inverse gas chromatography at infinite dilution

%Rh	T (K)	Van der Waals	Kiselev	Cylindrical	Redlih–Kwong	Spherical	Geometric
0%	480	134	145	156	237	329	141
	500	96	98	110	156	202	108
	520	113	110	122	184	241	114
	540	49	50	58	80	99	59
	560	119	116	130	195	247	125
0.25%	480	135	150	161	244	338	145
	500	96	98	111	157	203	108
	520	116	113	125	190	248	117
	540	50	51	59	81	101	60
	560	114	111	124	185	235	142
0.50%	480	139	150	162	245	341	146
	500	98	100	113	160	207	111
	520	114	111	123	186	244	115
	540	49	50	58	79	99	59
	560	117	114	128	191	242	123
0.75%	480	142	124	158	240	297	142
	500	97	100	112	159	206	110
	520	117	114	126	190	249	118
	540	47	48	55	79	95	57
	560	117	114	127	190	241	123
1.00%	480	131	143	154	233	323	139
	500	94	97	109	154	199	106
	520	114	111	123	186	243	115
	540	50	51	59	79	101	60
	560	120	117	131	196	249	126
1.25%	480	122	139	150	227	315	135
	500	91	92	106	149	193	103
	520	115	112	124	187	245	116
	540	48	49	57	78	97	58
	560	119	116	130	195	247	125
1.50%	480	122	136	146	221	307	132
	500	90	92	104	147	190	102
	520	113	111	122	185	243	115
	540	49	50	58	79	99	59
	560	118	115	129	192	244	124
1.75%	480	122	134	144	219	304	130
	500	89	91	103	146	188	101
	520	112	110	121	183	240	114
	540	50	51	59	81	101	60
	560	118	115	128	191	243	123
2.00%	480	135	135	145	220	306	131
	500	89	91	103	146	188	101
	520	112	109	121	183	240	113
	540	50	51	59	81	102	61
	560	120	117	131	195	248	126

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