Table 13 Values of \(\Delta {H}^{0}(kJ/mol)\), \(\Delta {S}^{0}(J {K}^{-1}{ mol}^{-1})\) and the expressions of \(\Delta {G}^{0}(T) (kJ/mol)\) of different polar and n-alkane molecules adsorbed on 2% of rhodium supported by H-β-zeolite.
Molecules | \(\Delta {H}^{0} (kJ/mol)\) | \(\Delta {S}^{0} (J {K}^{-1}{ mol}^{-1})\) | \(\Delta {G}^{0}(T) (kJ/mol)\) |
|---|---|---|---|
C5 | − 48.764 | − 67.9 | − 48.764 + 6.79 × 10–2 T |
C6 | − 54.787 | − 69.3 | − 54.787 + 6.93 × 10–2 T |
C7 | − 65.456 | − 80.9 | − 65.456 + 8.09 × 10–2 T |
C8 | − 73.026 | − 85.7 | − 73.026 + 8.57 × 10–2 T |
C9 | − 81.372 | − 92.2 | − 81.372 + 9.22 × 10–2 T |
Cyclohexane | − 42.018 | − 48.3 | − 42.018 + 4.83 × 10–2 T |
Tri-CE | − 48.668 | − 63.1 | − 48.668 + 6.31 × 10–2 T |
Tetra-CE | − 50.000 | − 62.5 | − 50.000 + 6.25 × 10–2 T |
Benzene | − 57.363 | − 72.6 | 57.363 + 7.26 × 10–2 T |
Chloroform | − 24.401 | − 31.7 | − 24.401 + 3.17 × 10–2 T |
Ether | − 31.179 | − 50.3 | − 31.179 + 5.03 × 10–2 T |
Methanol | − 41.654 | − 67.8 | − 41.654 + 6.78 × 10–2 T |
Acetone | − 43.644 | − 71.3 | − 43.644 + 7.13 × 10–2 T |
