Table 4 Comparison of the efficiency of NH4VO3 with other catalysts for synthesizing 1,4-DHP (1f.).

From: Ammonium metavanadate (NH4VO3): a highly efficient and eco-friendly catalyst for one-pot synthesis of pyridines and 1,4-dihydropyridines

Entry

Catalyst (amount of catalyst)

Condition

Time (min)

Yielda (%)

References

1

Nano-ZnO (10 mol%)

EtOH/r. t

50

83

46

2

Nano-g-Alumina (10 mg)

EtOH/r. t

50

85

44

3

Nano-ZMS-5 (10 mg)

EtOH/r. t

55

90

44

4

Succinic acid (0.5 mmol)

EtOH: H2O/80 (°C)

150

92

47

5

PhB(OH)2 (10 mol%)

EtOH/reflux

5 h

82

48

6

PPh3 (20 mol%)

EtOH/reflux

120

81

49

7

NH4VO3(15 mg)

EtOH/reflux

20

93

This work

  1. aIsolated yield.