Table 3 Comparison of catalytic activity of Fe3O4@YS-Ph-PMO/Pd nanocatalyst with previously reported catalytic systems in the reduction of nitrobenzene.

From: Magnetic yolk-shell structured periodic mesoporous organosilica supported palladium as a powerful and highly recoverable nanocatalyst for the reduction of nitrobenzenes

Entry

Catalyst

Conditions

Recovery times

Refs.

1a

γ-Fe2O3@SiO2–Pt@mSiO2

Hydrogen gas, EtOH, 40 °C

5

63

2b

γ-Fe2O3-MNAs

MeNHNH2, EtOH, 60 °C

7

64

3c

RHPrNH2@Ag

NaBH4, H2O, Reflux

4

65

4d

Fe3O4@nSiO2@mSiO2/Pr-Imi-NH2·Ag

NaBH4, H2O, 95 °C

4

66

5

Pd/SBA-15

Hydrogen gas, decane, EtOH, 313 K

5

67

6

Pt–Pd/PMO-SBA-15

Hydrogen gas, EtOH, 60 °C

5

68

7

Fe3O4@YS-Ph-PMO/Pd

NaBH4, H2O, RT

11

This work

  1. amSiO2, mesoporous silica.
  2. bMNAs, mesoporous nanoparticle assemblies.
  3. cRHPrNH2, rice husk-SiO2 aminopropylsilane.
  4. dPr-Imi, propylimidazolium.