Table 2 Comparative catalytic performance of MIP and UiO in epoxide ring-opening reactions with various alcoholic nucleophiles.
Entry | Catalyst | Epoxide | Alcohols (Nu) | Major product | Time | Conversion | Selectivity |
|---|---|---|---|---|---|---|---|
1 | MIP |
| CH3OH |
| 25 min | 99 | 99 |
2 | UiO |
| CH3OH |
| 2 h | 99 | 99 |
3 | MIP |
| CH3CH2OH |
| 10 h | 99 | 99 |
4 | UiO |
| CH3CH2OH |
| 8 h | 98 | 99 |
5 | MIP |
| CH3CH2CH2OH |
| 24 h | 30 | 99 |
6 | UiO |
| CH3CH2CH2OH |
| 24 h | 45 | 99 |
7 | MIP |
| CH3OH |
| 8 h | 99 | 99 |
8 | UiO |
| CH3OH |
| 8 h | 99 | 99 |
9 | MIP |
| CH3CH2OH |
| 18 h | 99 | 99 |
10 | UiO |
| CH3CH2OH |
| 18 h | 97 | 99 |
11 | MIP |
| CH3CH2CH2OH |
| 24 h | 38 | 99 |
12 | UiO |
| CH3CH2CH2OH |
| 24 h | 50 | 99 |
13 | MIP |
| CH3OH |
| 24 h | 8 | 99 |
14 | UiO |
| CH3OH |
| 24 h | 10 | 99 |
15 | MIP |
| CH3CH2OH |
| 24 h | 3 | 99 |
16 | UiO |
| CH3CH2OH |
| 24 h | 5 | 99 |
17 | MIP |
| CH3CH2CH2OH |
| 24 h | 0 | 99 |
18 | UiO |
| CH3CH2CH2OH |
| 24 h | 0 | 99 |
