Table 5 Comparative performance analysis of various catalysts in the ring-opening reaction of styrene oxide.
Catalyst | Nucleophile | Time (min) | Temperature (°C) | Yield (%) | TOF (h−1)a | References |
|---|---|---|---|---|---|---|
MIL-pip-SO3H | Methanol | 20 min | r.t | 99.4 | 91.1 | |
MIL-DABCO-SO3H | Methanol | 30 min | r.t | 98.3 | 89.4 | |
MIL-101(HPW) | Methanol | 20 min | 40 | 99 | 98.5 | |
Cu-MOF | Methanol | 120 min | r.t | 90 | 5.3 | |
Fe-BTC | Methanol | 60 min | 40 | 83 | 10 | |
HKUST-1 | Methanol | 150 min | 40 | 94 | 5.6 | |
PNVP/TiCl4 | Methanol | 15 min | r.t | 98 | 80 | |
MIL-101(Cr)-Pyz-RSO3H | Methanol | 20 min | r.t | 99 | 94 | |
MIP | Methanol | 25 min | r.t | 99 | 707 | This study |
MIP-a | Methanol | 25 min | r.t | 70 | 499 | This study |
UiO-66(CO2H)2 | Methanol | 120 min | 60 | 99 | 54 | This study |
Zr-BDC-MOF | Aniline | 10 min | 50 | 99.4 | 41 | |
Zn-BTC-MOF | Aniline | 10 min | 50 | 98.3 | 21 | |
Cu-BTC-MOF | Aniline | 10 min | 50 | 99 | 63 | |
AlCl3 | Aniline | 120 min | 60 | 98.7 | 49.6 | |
Al(Otf)3 | Aniline | 120 min | 60 | 82.5 | 43.65 | |
Sn(OTf)2 | Aniline | 120 min | 60 | 90.4 | 46.55 | |
[tespmim][OTf]-Al(OTf)3 | Aniline | 120 min | 60 | 99.9 | 49.95 | |
CaO-SiO2-IL | Aniline | 120 min | 60 | 51.13 | 37 | |
MIP | Aniline | 60 min | r.t | 99 | 107 | This study |
MIP-a | Aniline | 60 min | r.t | 62 | 67 | This study |
UiO-66-(CO2H)2 | Aniline | 120 min | 60 | 99 | 55.5 | This study |
