Table 2 CSA parameters of larval and adult cuticles at different carbon nuclei sites.
Carbon nuclei site as it is assigned in Figure-5 | \({\delta }_{iso}\) (ppm) | \({\delta }_{11}\) (ppm) | \({\delta }_{22}\) (ppm) | \({\delta }_{33}\) (ppm) | Span (ppm) | Anisotropy (ppm) | Asymmetry | Skew |
|---|---|---|---|---|---|---|---|---|
Principal components of CSA parameters of larval cuticle | ||||||||
1 | 173.3 | 252.9 ± 0.8 | 162.9 ± 0.6 | 104.0 ± 0.5 | 148.9 ± 0.80 | 119.5 ± 1.2 | 0.7 | \(- 0.2\) |
2 | 154.5 | 214.4 ± 1.3 | 166.5 ± 0.9 | 82.5 ± 0.8 | 131.9 ± 1.4 | − 107.9 ± 1.3 | 0.7 | 0.3 |
First line corresponds to chemical ‘4’ | 137.7 | 152.8 ± 0.4 | 136.4 ± 0.3 | 123.9 ± 0.3 | 28.9 ± 0.6 | 22.2 ± 0.7 | 0.8 | \(- 0.1\) |
Second line corresponds to chemical ‘4’ | 129.3 | 152.0 ± 0.7 | 127.9 ± 0.6 | 108.0 ± 0.5 | 43.9 ± 0.8 | 34.0 ± 1.1 | 0.9 | \(- 0.1\) |
5 | 116.5 | 137.3 ± 0.6 | 115.7 ± 0.5 | 96.5 ± 0.4 | 40.7 ± 0.6 | 31.1 ± 0.9 | 0.9 | \(- 0.05\) |
First line corresponds to chemical ‘6’ | 104.2 | 123.3 ± 0.5 | 103.2 ± 0.4 | 86.1 ± 0.4 | 37.2 ± 0.6 | 28.6 ± 0.8 | 0.9 | \(- 0.07\) |
Second line corresponds to chemical ‘6’ | 99.2 | 121.0 ± 0.7 | 99.0 ± 0.5 | 77.5 ± 0.4 | 43.6 ± 0.7 | 32.8 ± 1.0 | 1.0 | 0.0 |
Third line corresponds to chemical ‘6’ | 93.5 | 105.0 ± 0.2 | 94.1 ± 0.1 | 81.3 ± 0.1 | 23.7 ± 0.3 | − 18.2 ± 0.2 | 0.9 | 0.08 |
7 | 83.6 | 104.2 ± 0.6 | 81.8 ± 0.5 | 64.8 ± 0.4 | 39.4 ± 0.7 | 30.9 ± 0.9 | 0.8 | \(- 0.1\) |
8 | 75.5 | 109.7 ± 0.7 | 63.4 ± 0.6 | 53.4 ± 0.4 | 56.3 ± 0.6 | 51.3 ± 1.1 | 0.3 | \(- 0.6\) |
9 | 73.5 | 93.3 ± 0.4 | 72.5 ± 0.3 | 54.6 ± 0.2 | 38.6 ± 0.4 | 29.7 ± 0.5 | 0.9 | \(- 0.07\) |
10 | 60.8 | 79.8 ± 0.6 | 57.2 ± 0.4 | 45.7 ± 0.4 | 34.5 ± 0.7 | 28.5 ± 0.9 | 0.6 | \(- 0.3\) |
First line corresponds to chemical ‘11’ | 55.0 | 69.9 ± 0.3 | 54.0 ± 0.2 | 41.0 ± 0.2 | 28.9 ± 0.4 | 22.4 ± 0.5 | 0.9 | \(- 0.1\) |
Second line corresponds to chemical ‘11’ | 49.0 | 65.2 ± 0.3 | 48.2 ± 0.2 | 33.6 ± 0.2 | 31.5 ± 0.4 | 24.2 ± 0.5 | 0.9 | \(- 0.08\) |
12 | 40.0 | 59.7 ± 0.7 | 35.5 ± 0.5 | 24.7 ± 0.5 | 35.0 ± 0.8 | 29.6 ± 1.0 | 0.5 | \(- 0.4\) |
13 | 33.3 | 44.0 ± 0.1 | 30.1 ± 0.07 | 25.7 ± 0.10 | 18.4 ± 0.1 | 16.1 ± 0.2 | 0.4 | \(- 0.5\) |
14 | 30.2 | 43.5 ± 0.2 | 28.5 ± 0.1 | 18.5 ± 0.1 | 25.0 ± 0.3 | 20.0 ± 0.3 | 0.7 | \(- 0.2\) |
First line corresponds to chemical ‘15’ | 26.0 | 34.7 ± 0.05 | 24.6 ± 0.03 | 18.7 ± 0.03 | 16.0 ± 0.05 | 13.0 ± 0.11 | 0.7 | \(- 0.3\) |
Second line corresponds to chemical ‘15’ | 23.5 | 32.5 ± 0.2 | 24.0 ± 0.1 | 13.9 ± 0.2 | 18.5 ± 0.3 | − 14.3 ± 0.3 | 0.9 | \(0.09\) |
First line corresponds to chemical ‘16’ | 19.5 | 30.7 ± 0.2 | 18.3 ± 0.1 | 9.5 ± 0.2 | 21.2 ± 0.3 | 16.8 ± 0.3 | 0.8 | \(- 0.2\) |
Second line corresponds to chemical ‘16’ | 16.0 | 29.8 ± 0.2 | 12.0 ± 0.1 | 6.0 ± 0.1 | 23.7 ± 0.3 | 20.7 ± 0.3 | 0.4 | \(- 0.5\) |
Third line corresponds to chemical ‘16’ | 13.0 | 26.4 ± 0.2 | 9.6 ± 0.1 | 3.0 ± 0.1 | 23.3 ± 0.3 | 20.0 ± 0.3 | 0.5 | \(-0.4\) |
Principal components of CSA parameters of adult cuticle | ||||||||
1 | 173.3 | 254.4 ± 0.9 | 160.0 ± 0.7 | 105.5 ± 0.6 | 148.9 ± 0.9 | 121.7 ± 1.4 | 0.6 | \(- 0.2\) |
2 | 157.0 | 230.5 ± 2.6 | 154.9 ± 1.9 | 85.5 ± 1.6 | 145.0 ± 2.6 | 110.3 ± 3.8 | 0.9 | \(- 0.04\) |
3 | 144.0 | 179.3 ± 1.6 | 142.7 ± 1.3 | 109.9 ± 1.1 | 69.4 ± 1.7 | 53.0 ± 2.5 | 0.9 | \(- 0.05\) |
First line corresponds to chemical ‘4’ | 136.5 | 153.8 ± 0.6 | 136.9 ± 0.3 | 118.9 ± 0.5 | 34.9 ± 0.9 | − 26.4 ± 0.7 | 0.9 | 0.03 |
Second line corresponds to chemical ‘4’ | 129.3 | 146.4 ± 0.5 | 127.0 ± 0.3 | 114.4 ± 0.4 | 32.0 ± 0.7 | 25.7 ± 0.7 | 0.7 | \(- 0.2\) |
5 | 117.0 | 138.9 ± 0.4 | 112.5 ± 0.2 | 99.6 ± 0.3 | 39.2 ± 0.5 | 32.8 ± 0.5 | 0.5 | \(- 0.3\) |
First line corresponds to chemical ‘6’ | 104.0 | 121.2 ± 0.1 | 103.3 ± 0.07 | 87.5 ± 0.07 | 33.7 ± 0.1 | 25.8 ± 0.1 | 0.9 | \(- 0.06\) |
Second line corresponds to chemical ‘6’ | 94.2 | 113.9 ± 0.4 | 95.3 ± 0.2 | 73.3 ± 0.3 | 40.6 ± 0.5 | − 31.2 ± 0.4 | 0.8 | 0.08 |
7 | 83.6 | 116.3 ± 0.2 | 67.3 ± 0.2 | 67.3 ± 0.1 | 49.0 ± 0.2 | 49.0 ± 0.3 | 0.0 | \(- 1.0\) |
8 | 75.6 | 93.2 ± 0.1 | 66.8 ± 0.09 | 66.7 ± 0.09 | 26.5 ± 0.1 | 26.4 ± 0.2 | 0.0 | \(- 1.0\) |
9 | 73.5 | 95.9 ± 0.3 | 66.5 ± 0.2 | 58.0 ± 0.2 | 37.9 ± 0.4 | 33.6 ± 0.4 | 0.3 | \(- 0.5\) |
10 | 60.8 | 82.5 ± 0.2 | 56.1 ± 0.1 | 43.7 ± 0.1 | 38.8 ± 0.3 | 32.6 ± 0.3 | 0.5 | \(- 0.3\) |
First line corresponds to chemical ‘11’ | 55.0 | 74.2 ± 0.1 | 53.4 ± 0.08 | 37.3 ± 0.08 | 36.9 ± 0.1 | 25.8 ± 0.2 | 0.8 | \(- 0.1\) |
Second line corresponds to chemical ‘11’ | 49.0 | 70.4 ± 0.2 | 49.1 ± 0.1 | 27.5 ± 0.1 | 42.8 ± 0.3 | − 32.2 ± 0.2 | 0.9 | 0.01 |
12 | 40.0 | 63.6 ± 0.6 | 40.5 ± 0.4 | 15.8 ± 0.4 | 47.7 ± 0.8 | − 36.2 ± 0.7 | 0.9 | 0.03 |
13 | 33.3 | 54.4 ± 0.2 | 28.8 ± 0.1 | 16.7 ± 0.1 | 37.7 ± 0.2 | 31.6 ± 0.2 | 0.5 | \(- 0.3\) |
14 | 30.2 | 40.8 ± 0.05 | 28.8 ± 0.04 | 20.9 ± 0.03 | 19.9 ± 0.05 | 15.9 ± 0.07 | 0.7 | \(- 0.2\) |
First line corresponds to chemical ‘15’ | 25.0 | 35.9 ± 0.07 | 26.4 ± 0.05 | 12.6 ± 0.05 | 23.3 ± 0.09 | − 18.5 ± 0.08 | 0.7 | 0.1 |
Second line corresponds to chemical ‘15’ | 23.0 | 33.3 ± 0.02 | 24.4 ± 0.02 | 11.3 ± 0.01 | 22.0 ± 0.01 | − 17.5 ± 0.02 | 0.7 | 0.1 |
First line corresponds to chemical ‘16’ | 19.5 | 36.6 ± 0.10 | 15.8 ± 0.07 | 6.1 ± 0.07 | 30.5 ± 0.13 | 25.6 ± 0.1 | 0.5 | \(- 0.3\) |
Second line corresponds to chemical ‘16’ | 16.0 | 32.1 ± 0.13 | 7.9 ± 0.08 | 7.9 ± 0.10 | 24.2 ± 0.18 | 24.2 ± 0.2 | 0.0 | \(- 1.0\) |
Third line corresponds to chemical ‘16’ | 12.4 | 19.7 ± 0.05 | 11.7 ± 0.03 | 5.8 ± 0.04 | 13.9 ± 0.08 | 10.9 ± 0.08 | 0.8 | \(- 0.1\) |
