Table 1 Crystal data and structure refinement for [N(CH3)4]2MnCl4 at 250 K and 300 K.
Chemical formula | C8H24N2MnCl4 | C8H24N2MnCl4 |
|---|---|---|
Weight | 345.03 | 345.03 |
Crystal system | Monoclinic | Orthorhombic |
Space group | P21/n | Pnma |
T (K) | 250 | 300 |
a (Å) | 9.0412 (4) | 9.0837 (6) |
b (Å) | 37.0067 (14) | 12.3777 (8) |
c (Å) β (°) | 15.5885 (6) 90.3000 (10) | 15.7211 (8) 90 |
Z | 12 | 4 |
V (Å3) | 5215.6 (4) | 1767.61 (19) |
Radiation type | Mo-Kα | Mo-Kα |
Wavelength (Å) | 0.71073 | 0.71073 |
Reflections collected | 99,336 | 15,180 |
Independent reflections | 12,919 (Rint=0.1043) | 2333 (Rint=0.0643) |
Goodness-of-fit on F2 | 1.024 | 1.050 |
Final R indices [I > 2sigma(I)] | R1 = 0.0554, wR2 = 0.1273 | R1 = 0.0801, wR2 = 0.2488 |
R indices (all data) | R1 = 0.1533, wR2 = 0.1683 | R1 = 0.1496, wR2 = 0.3050 |
