Table 7 Un-compensated solution resistance, admittance, charge transfer resistance, double layer capacitance and thickness of passive film for rebar exposed in pore solution mixed with different additives.
Test solution | Electrochemical parameters | IE | χ2 x10−4 | |||||
|---|---|---|---|---|---|---|---|---|
R0 (Ohm .cm2) | Y0 (S.sα / cm2) x10−6 | α | Rct (KOhm .cm2) | Cdl,µF cm−2 | Thickness, nm | % | 2.1 | |
a. Pore solution + 1 M NaCl | 4.9 | 59.5 | 0.78 | 11.80 | 6.02 | 3.82 | - | 9.6 |
b. a + 0.125%GA | 4.67 | 45.3 | 0.81 | 74.38 | 6.25 | 6.37 | 84.1 | 2.1 |
c. b + 0.10% CaCl2 | 4.8 | 39.4 | 0.80 | 425.5 | 4.62 | 8.62 | 97.22 | 6.3 |
d. b + 0.20% CaCl2 | 5.2 | 28.2 | 0.81 | 560.1 | 3.52 | 11.32 | 97.9 | 4.2 |
e. b + 0.25%CaCl2 | 5.9 | 25.1 | 0.80 | 429.5 | 2.75 | 14.48 | 97.25 | 4.1 |