Table 2 Spectroscopic polarity parameters, physical properties and polarity functions of the employed solvents31,39 and LCs40,41,42.

From: Solvent polarity effect on photophysical properties of some aromatic azo dyes with focus on tautomeric and toxicity competition

Solvent

ε

n

α

β

π*

\(f(\varepsilon ,n)_{B}\)

\(f(\varepsilon ,n)_{KCV}\)

Cyclohexane

2.02

1.42

0.00

0.00

0.00

0.00

0.29

1,4–Dioxane

2.22

1.42

0.00

0.37

0.49

0.04

0.31

Chlorobenzene

5.62

1.52

0.00

0.06

0.65

0.39

0.54

1–Decanol

8.00

1.43

0.70

0.85

0.45

0.55

0.57

1-Heptanol

11.30

1.42

0.64

0.96

0.39

0.65

0.61

Methylamine

12.65

1.35

0.64

0.78

0.98

0.70

0.59

Dimethylamine

5.30

1.34

0.66

0.80

0.95

0.45

0.50

1–Hexanol

13.00

1.41

0.67

0.94

0.40

0.69

0.63

1-Butanol

17.40

1.39

0.84

0.84

0.47

0.75

0.64

2–Propanol

19.90

1.37

0.76

0.84

0.48

0.78

0.65

Ethanol

24.30

1.36

0.86

0.75

0.54

0.81

0.65

Methanol

33.70

1.32

0.98

0.66

0.60

0.86

0.65

Ethylene glycol

37.00

1.43

0.90

0.52

0.92

0.83

0.71

DMF

39.25

1.43

0.00

0.69

0.88

0.84

0.71

DMSO

47.24

1.47

0.00

0.76

1.00

0.84

0.74

Water

78.40

1.33

1.17

0.47

1.09

0.91

0.68

Solvent

ε

n

\({T}_{C}/^\circ{\rm C}\)

α

β

π*

\(f(\varepsilon ,n)_{B}\)

\(f(\varepsilon ,n)_{KCV}\)

ML-0643

5.60

1.52

80.00

0.26

0.54

0.55

0.39

0.54

MLC-6292

6.20

1.50

120.0

0.33

0.55

0.56

0.44

0.55

MAT-160968

12.00

1.57

72.70

0.49

0.49

0.46

0.60

0.68

MLC-2082

20.60

1.56

89.90

0.36

0.58

0.62

0.71

0.73

MLC-2053

22.10

1.59

86.00

0.29

0.58

0.62

0.72

0.75

MLC-2144

23.70

1.59

113.0

0.35

0.68

0.81

0.72

0.76