Table 5 Comparison of the catalytic activity of Fe–N–C/DDQ catalyst system in the oxidation of diethyl 2,6-dimethyl-4-phenyl-1,4-dihydropyridine-3,5-dicarboxylate with some reported procedures.
Entry | Catalyst | Reaction conditions | Time (h) | Isolated yield (%) | References |
|---|---|---|---|---|---|
1 | NHPI (10 mol%)/Co(OAC)2 (0.5 mol%) | CH3CN, O2, Reflux | 4 h | 99 | |
2 | Laccase (200 U)/4-phenyl urazole (20 mol%) | NaPBS/CH3CN,O2, 40 °C | 22 h | 99 | |
3 | Laccase (168 U)/ABTS (10 mol%) | Acetate buffer/MeOH, air, 50 °C | 9 h | 80 | |
4 | AuCNT (10 mol%)/2,5-dichlorocyclohexa-2,5-diene-1,4-dione (200 mol%) | CHCl3/H2O | 36 h | 78 | |
5 | Fe–N–C (70 mg, 4.3 mol% of Fe), DDQ (10 mol%), O2 (balloon) | H2O/MeCN, R. T | 6.51 h | 94 | This work |