Table 1 Reaction conditions of the synthesis of PHB-Poleox, PHB-Priciox, and PHB-Plinaox macroperoxide initiators in CH2Cl2 (20 mL). γ∗ (Vns: petroleum ether, Vs: Chloroform); γ∗∗ (Vns: Methanol, Vs: Chloroform).

From: Synthesis and characterization of branched multiblock copolymers of polyhydroxybutyrate (PHB) autoxidized fatty acid and polymethylmethacrylate (PMMA)

Code

PHBdOH (g)

PLinaox-65 (g)

Poleox-345 (g)

Priciox-345 (g)

Yield

(g)

DCC

(g)

DMAP

(g)

γ∗

(Vns /Vs)

PHBdPlina65ox

1.28

0.86

-

-

0.73

0.92

0.17

1.8-2.0

PHBdPole-345ox

1.51

-

0.96

-

1.39

0.91

0.27

1.8-2.0

PHBdPrici-345ox

1.55

-

-

0.96

1.96

0.93

0.23

1.8-2.0

        

γ∗∗

(Vns /Vs)

PHBdPlinaox-1

2.15

1.50

-

-

2.55

2.18

0.65

2.3-3.0

PHBdPlinaox-2

2.58

1.58

-

-

3.62

3.32

0.50

2.3-3.0

PHBdPoleox-1

2.18

-

2.34

-

2.06

2.71

0.47

2.5-3.0

PHBdPriciox-1

2.27

-

-

2.12

2.12

2.08

0.37

3.0-3.6

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