Table 4 Frequencies of important groups of the complexes.
Complex 1 | Complex 2 | ||
|---|---|---|---|
Group | ν (cm−1) | Group | ν (cm−1) |
NH2 (Stretching Aromatic) | 3335, 3412 | NH2 (Stretching) | 3330, 3412 |
C=N | 1618 | C=N | 1623 |
C=C (Aromatic) | 1545 | C=C (Aromatic) | 1551 |
C-H (Stretching Aromatic) | 3154 | C-H (Stretching Aromatic) | 3155 |
C-H (Aliphatic) | 2924 | C-H (Aliphatic) | 2703 |
C=O | 1644 | C=O | 1745 |
C-H (Acetylacetone) | 2852 | O-H | 3484 |
C-N | 1397 | C-N | 1404 |
C-H (Bending Aromatic) | 780 | C-H (Bending Aromatic) | 779 |
NH2(Out-of-plane bending) | 826 | NH2(Out-of-plane bending) | 827 |