Table 5 The δh parameter values of NADES, predicted using Semi- (SEM) (Hans—Hansen’s model (Eq. 17); ψHans-TW—same as Hans, but using the specific energies obtained from FTIR spectrum instead of the constant 5000 cal/mol proposed by Hansen (see more information in Table S.14 and Figure S.1 and S.2) and Empirical models (EM) (StP—Stefanis and Panayiotou; HK—Hoftyzer and Van Krevelen; HKF—Hoftyzer-Van Krevelen and Fedors; Ymt—Yamamoto).

From: Application of Hansen solubility parameters in the eutectic mixtures: difference between empirical and semi-empirical models

NADES

δh

SEM

EM

Hans

Hans-TWψ

StP

HK

HKF

Ymt

Bet:Glc:W (5:2:10)

107.81

103.96

23.32

20.32

22.13

13.83

Bet:Gly:Suc:W (2:3:1:5)

92.48

89.57

35.01

24.23

26.90

15.23

Bet:Suc:Pro:W (5:2:2:21)

159.04

153.62

32.59

22.48

24.34

16.46

Fru:Glc:Suc:W (1:1:1:10)

127.85

123.68

50.68

31.22

36.99

22.83

Glc:Pro:Gly:W (3:5:3:20)

181.48

174.80

29.93

25.42

28.07

20.61

Gly:Fru (4:1)

65.91

63.97

33.80

27.97

32.85

17.02

Gly:Fru:Sorb:W (1:1:1:3)

82.64

80.21

42.88

30.46

36.25

20.50

Gly:Glc (4:1)

65.85

63.90

33.47

28.43

32.67

17.21

Gly:Glc:Sorb:W (1:1:1:3)

82.51

79.82

42.85

31.05

36.18

20.84

Gly:Suc:Sorb:W (2:1:2:10)

135.47

131.05

48.96

32.05

36.33

22.22

Gly:Tre:Sorb:W (2:1:2:10)

134.43

130.04

48.86

32.27

36.32

22.45

Pro:Gly:Sorb:W (1:1:1:13)

153.13

148.13

50.29

33.78

37.28

25.65

Tre:Fru:W (1:2:13)

146.10

141.31

49.86

31.94

37.40

24.30

Tre:Glc:W (1:2:13)

145.99

141.21

50.08

32.63

37.36

24.80

Men:AcetA (1:1)

19.02

18.69

10.83

11.60

11.31

5.82

Men:Bor (7:2)

33.22

32.45

10.92

11.11

11.11

3.21

Men:DecA (1:1)

15.14

15.00

9.15

8.99

8.89

3.92

Men:DecA (2:1)

18.69

18.31

9.68

9.64

9.50

3.68

Men:DecA (4:1)

24.28

23.75

10.13

10.18

10.01

3.48

Men:DecA (7:2)

32.55

31.80

10.05

10.09

9.93

3.51

Men:LauA (2.7:1)

20.32

19.84

9.52

9.57

9.43

3.45

Men:LauA (2:1)

18.14

17.71

9.24

9.26

9.14

3.51

Men:LauA (4.5:1)

25.07

24.45

9.92

10.02

9.86

3.36

Men:LauA (4:1)

23.84

23.30

9.84

9.92

9.77

3.38

Men:LauA (5.3:1)

26.92

26.22

10.03

10.14

9.97

3.34

Men:LauA (8:1)

32.37

31.64

10.26

10.40

10.22

3.29

Men:LauA:DecA (2:1:1)

20.94

20.73

8.85

8.74

8.66

3.78

Men:LauA:DecA (4:1:1)

26.04

25.51

9.45

9.44

9.32

3.59

Men:LevA (1:1)

17.38

17.23

10.36

10.96

10.77

5.35

Men:MyrA (4:1)

23.43

22.93

9.51

9.68

9.54

3.29

Men:MyrA (8:1)

32.05

31.32

10.07

10.25

10.07

3.23

Men:Thy (1:1)

15.99

15.62

10.58

11.19

10.88

3.56

Men:Thy (2:1)

19.39

18.91

10.67

11.14

10.86

3.42

Men:Thy (4:1)

24.83

24.22

10.73

11.10

10.85

3.32

Men:Thy (8:1)

33.12

32.36

10.78

11.07

10.83

3.25

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