Table 7 Model parameters of Fe@BC and BC for Pb(II), Cu(II), and Ni(II).
From: Adsorption of Fe-modified peanut shell biochar for Pb(II) in mixed Pb(II), Cu(II), Ni(II) solutions
Model | Parameters | BC | Fe@BC | ||||
|---|---|---|---|---|---|---|---|
Metal ions | |||||||
Pb | Cu | Ni | Pb | Cu | Ni | ||
LIM | Qm | 16.625 | 10.865 | 0.497 | 23.245 | 21.551 | 0.736 |
kL | 0.109 | − 0.176 | − 1.677 × 1016 | 0.313 | − 0.274 | − 6.383 × 1018 | |
R2 | 0.836 | 0.938 | 4.441 × 10–16 | 0.752 | 0.617 | − 1.110–15 | |
FIM | kf | 7.550 | 20.499 | 9.687 × 10–7 | 15.804 | 40.802 | 9.450 × 10–6 |
n | 6.473 | − 7.853 | 0.337 | 12.524 | − 7.222 | 0.392 | |
R2 | 0.903 | 0.988 | 0.976 | 0.898 | 0.814 | 0.935 | |
LFIM | QLF | 95.357 | 18.549 | 1.323 | 85.305 | 27.201 | 1.931 |
kLF | 1.108 × 10–6 | 0.003 | 0.011 | 7.674 × 10–7 | 0.006 | 0.011 | |
nLF | 0.181 | − 0.378 | 6.265 | 0.106 | − 1.844 | 5.292 | |
R2 | 0.902 | 0.990 | 0.997 | 0.894 | 0.969 | 0.956 | |
HeIM | kH | 0.037 | − 0.025 | 0.016 | 0.035 | − 0.080 | 0.021 |
CH | 11.784 | 13.855 | − 0.739 | 19.556 | 28.512 | − 0.917 | |
R2 | 0.925 | 0.965 | 0.943 | 0.975 | 0.953 | 0.921 | |
RPIM | a | 423.947 | 0.345 | 7.240 × 1012 | 871.548 | 0.026 | 3.913 × 108 |
kRP | 3.202 × 103 | 8.323 | 0.011 | 1.378 × 104 | 3.757 | 0.016 | |
nRP | 0.846 | 1.160 | − 6.810 | 0.920 | 1.416 | − 4.570 | |
R2 | 0.903 | 0.990 | 0.997 | 0.898 | 0.995 | 0.950 | |
KCIM | AKC | 1.677 | 168.171 | 0.015 | 2.333 | 3.706 × 105 | 0.028 |
nKC | 0.020 | − 0.378 | 0.341 | 0.009 | − 1.835 | 0.314 | |
kKC | − 0.803 | 9.064 | − 0.187 | − 0.857 | 1.362 × 104 | − 0.211 | |
R2 | 0.910 | 0.990 | 0.912 | 0.907 | 0.969 | 0.868 | |
SIM | Qsips | 1621.323 | 18.551 | 1.323 | 4.247 × 104 | 27.212 | 2.147 |
ksips | 0.005 | 9.071 | 6.367 × 10–13 | 0.004 | 1.363 × 104 | 6.823 × 10–10 | |
nsips | 0.156 | − 0.378 | 6.266 | 0.080 | − 1.835 | 4.661 | |
R2 | 0.903 | 0.990 | 0.997 | 0.898 | 0.969 | 0.955 | |
HiIM | QHill | 1.072 × 104 | 18.551 | 1.323 | 1.082 × 104 | − 1.702 × 105 | 2.169 |
nHill | 0.155 | − 0.378 | 6.266 | 0.080 | − 0.138 | 4.612 | |
kHill | 1419.055 | 0.110 | 1.574 × 1012 | 683.656 | − 4.170 × 103 | 1.200 × 109 | |
R2 | 0.903 | 0.990 | 0.997 | 0.898 | 0.814 | 0.955 | |