Table 6 Chemical composition of marjoram methanolic extract identified by HPLC and effect of Ch–Cu NPs on the content of polyphenolic compounds of infected marjoram plants.
No | Retention time (min) | Compounds | Control | Concentrations of Ch-Cu NPs | |||||
|---|---|---|---|---|---|---|---|---|---|
25mg/L | 50mg/L | 100mg/L | |||||||
Tm | F | Tm | F | Tm | F | ||||
1 | 6.37 | Gallic acid | 6.73 | 7.15 | 1.06 | 8.98 | 1.33 | 7.55 | 1.12 |
2 | 12.25 | Chlorogenic acid | 5.81 | 5.97 | 1.03 | 7.79 | 1.34 | 8.11 | 1.40 |
3 | 14.03 | Vanillic acid | 9.15 | 10.54 | 1.11 | 11.74 | 1.28 | 10.55 | 1.15 |
4 | 15.19 | Caffeic acid | 8.24 | 10.57 | 1.28 | 15.83 | 1.92 | 14.84 | 1.80 |
5 | 21.78 | Coumaric acid | 13.87 | 17.28 | 1.25 | 17.61 | 1.27 | 18.15 | 1.30 |
6 | 23.36 | Ferulic acid | 12.52 | 13.94 | 1.11 | 15.37 | 1.22 | 14.25 | 1.73 |
7 | 29.61 | Benzoic acid | 5.69 | 6.27 | 1.10 | 7.19 | 1.26 | 7.11 | 1.24 |
8 | 32.11 | Rutin | 6.51 | 6.59 | 1.01 | 6.82 | 1.05 | 6.67 | 1.03 |
9 | 33.74 | Rosmarinic acid | 8.19 | 10.21 | 1.91 | 10.96 | 1.33 | 10.77 | 1.31 |